The fuel cell works by processing a hydrogen-rich fuel—usually natural gas or methanol—into hydrogen, which, when combined with oxygen, produces electricity and water. This is the reverse electrolysis process.
Rather than burning the fuel, however, the fuel cell converts the fuel to electricity using a highly efficient electrochemical process. A fuel cell has few moving parts, and produces very little waste heat or gas.
A fuel cell power plant is basically made up of three subsystems or sections. In the fuel-processing section, the natural gas or other hydrocarbon fuel is converted to a hydrogen-rich fuel. This is normally accomplished through what is called a steam catalytic reforming process.
The fuel is then fed to the power section, where it reacts with oxygen from the air in a large number of individual fuel cells to produce direct current (DC) electricity, and by-product heat in the form of usable steam or hot water.
For a power plant, the number of fuel cells can vary from several hundred (for a 40-kW plant) to several thousand (for a multi-megawatt plant). In the final, or third stage, the DC electricity is converted in the power conditioning subsystem to electric utility-grade alternating current (AC).
In the power section of the fuel cell, which contains the electrodes and the electrolyte, two separate electrochemical reactions take place: an oxidation half-reaction occurring at the anode and a reduction half-reaction occurring at the cathode.
The anode and the cathode are separated from each other by the electrolyte. In the oxidation half-reaction at the anode, gaseous hydrogen produces hydrogen ions, which travel through the ionically conducting membrane to the cathode. At the same time, electrons travel through an external circuit to the cathode.